Integrated soil and groundwater remediation project at an industrial site affected by a spill of volatile organic compounds and heavy metals

Project type: Remediation of saturated and unsaturated zones contaminated by heavy metals, hydrocarbons, BTEX, CVOCs, and ketones. 
Contamination plume in groundwater: 25,000 m² 
Affected soil surface area: 1,800 m² 

Conceptual framework: 

  • Industrial site for liquid compound recycling. Pollution caused by a point discharge of stored compounds as a result of a fire. The spilled substances reached the river, surrounding areas, streets, and the aquifer. 
  • Project duration: 4 years. 

Remediation: 

  • Preliminary delineation of contamination plume in both soil and groundwater. 
  • On-site pilot tests to determine the scale of the pumping and soil treatment system. 
  • Installation of a treatment system with 12 pumping wells. 
  • Soil stockpiles for treatment, aiming to reduce the volume requiring management. 
  • Excavation and direct management of highly contaminated soils. 
  • Treatment system including decantation, phase separation, stripping, and activated carbon. 
  • Venting/sparging treatment at the contamination source. 

Objective: 

  • Reduction of dissolved compounds to concentrations below the established remediation targets. 
  • Removal of contaminated soils in the river area. 
  • Selective excavation in the contamination hotspot. 

Data: 

  • Groundwater plume: 25,000 m² 
  • Treated water volume: 3,500 m³ 
  • Treated vapor volume: 1,143,300 m³ 
  • Excavated non-hazardous soil: 1,671 T 
  • Excavated hazardous soil: 106 T 
  • Treated and reused soil on-site: 400 m³ 

Emergency actions: 

  • Delimitation and removal of 250 m³ of contaminated soil in and around the riverbed. 
  • Soil replacement. 
  • Replanting of vegetation. 
  • Installation of a hydraulic barrier for containment. 

Groundwater remediation: 

  • Water treatment system via pump & treat with 12 pumping wells distributed across the entire plume area, using 3” pumps. Functions as a downstream hydraulic barrier and treatment extraction system.
  • Treatment starts with decantation and homogenization in a 30 m³ tank with level sensors to prevent overflow. Transfer pumps feed a stripping tower (capacity 36 m³/h), separating volatile and liquid phases. 
  • The volatile phase is filtered through air activated carbon filters before atmospheric release. 
  • The liquid phase passes through a coalescing hydrocarbon separator, then through a 17 m³ water filter containing 8.5 T of activated carbon. 
  • Finally, treated water is stored in a 30 m³ buffer tank (3-hour retention capacity), monitored by a continuous COD analysers (15-min readings). Discharge is permitted when COD is below the threshold. The system automatically stops and retains the water if limits are exceeded. 

 Remediation goals achieved after 3 years of treatment. 

Soil remediation: 
Selective excavation according to disposal route. 
For less contaminated soils with reuse potential, vapor extraction is applied using a biopile to eliminate volatile compounds. 

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